Catalysis by Metals and Alloys - book by Ponec, V.;Bond, G.C.
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DESCRIPTION: The theoretical basis of chemisorption and catalysis by metals and alloys, and their use in a range of model and industrially significant catalysed processes are described in this book.Model, as well as industrially used reactions catalyzed by alloys are reviewed, among them the Fischer-Tropsch synthesis, reactions of alkanes ('reforming'-reactions), oxidations, hydro-/dehydrogenation, decomposition of methanoic acid, deuterium exchange reactions (H2, hydrocarbons) and to a lesser extent some others. This review on catalytic reactions, with results from the available information, is introduced in two chapters which summarize the definition, the physical meaning and the role of such factors as ligand (electronic structure), ensemble size (geometrical) and ensemble composition effects. The assessment of the roles of these individual factors requires the knowledge of several physical techniques and a proper evaluation of the results TABLE OF CONTENTS: Prologue. 1. Structure and properties of metals and alloys. 2. Experimental techniques of solid state physics, relevant to research on alloys. 3. The electronic structure of alloys; experimental results. 4. Surface composition of alloys. 5. Physical properties and structures of small metal and alloy particles. 6. The catalytic cycle. 7. Preparation and characterization of metal and alloy catalysts. 8. Adsorption on alloys. 9. Catalysis by alloys - general features. 10. Reactions of hydrogen and alkane-deuterium exchange. 11. Catalytic hydrogenation and dehydrogenation. 12. Oxidation reactions. 13. Reactions of alkanes and reforming of naphtha. 14. Syngas reactions. Epilogue. Subject index. AUTHORS: Ponec, V.;Bond, G.C. PAGES: 744 pages PUBLISH DATE: 01/01/2003 ISBN Number: 0-444-89796-8
USA Book Price: $304.95
UK Book Price: £203
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